GIS中曲线综合模型的建立及拓展

针对地图中水系、道路、境界线等线状要素的制图综合中的图形简化问题,利用小波分析的多分辨率分析原理,建立多分辨率小波分析思想和空间数据多尺度表达之间关系,提出了线状要素空间多尺度表达数学模型。对线状要素进行综合和平滑,实现了线状要素的空间多尺度表达。结合实例探讨了数学模型的特点、拓扑一致性和模型拓展等问题。     

固体酸催化合成环已酮1,2-丙二醇缩酮进展

评述了对甲苯磺酸、氨基磺酸、强酸性阳离子交换树脂、六水三氯化铁、二水氯化亚锡、硫酸铜、水合硫酸铁、十二水合硫酸铁铵、硫酸钛、四水硫酸铈、铌酸、树脂固载Lewis酸、一水硫酸氢钠、碘、固体超强酸、杂多酸、分子筛和维生素C等催化剂催化合成环已酮1,2-丙二醇缩酮的实验结果.建议对近年来开发的有应用前景的催化剂进行扩大试验与筛选.     

一种新型吡啶盐的合成、结构表征及光学性质研究

合成了一种新型有机荧光染料4-[4′-(N,N-二丁基胺基)苯乙烯基]-N-甲基吡啶四氟硼酸盐,并通过元素分析、红外光谱、热重(TGA)分析、电喷雾质谱等对其进行了表征,并测试了其紫外-可见电子光谱和在8种不同溶剂中的单光子荧光光谱等线性光学性质,同时对其进行了初步的研究.     

A high-level synthesis based dual-module redundancy with multi-residue detection （DMR-MRD） fault-tolerant method for on-board processing satellite communication systems

On board processing （OBP） satellite systems have obtained more and more attentions in recent years because of their high efficiency and performance.However,the OBP transponders are very sensitive to the high energy particles in the space radiation environments.Single event upset （SEU） is one of the major radiation effects,which influences the satellite reliability greatly.Triple modular redundancy （TMR） is a classic and efficient method to mask SEUs.However,TMR uses three identical modules and a comparison logic,the circuit size becomes unacceptable,especially in the resource limited environments such as OBP systems.Considering that,a new SEU-tolerant method based on residue code and high-level synthesis （HLS） is proposed,and the new method is applied to FIR filters,which are typical structures in the OBP systems.The simulation results show that,for an applicable HLS scheduling scheme,area reduction can be reduced by 48.26％ compared to TMR,while fault missing rate is 0.15％.     

Template/surfactant free and UV light irradiation assisted fabrication of Mn-Co oxides composite nanorings: Structure and synthesis mechanism

A facile, green, cost effective, and template or surfactant free strategy via a two-step route i.e. UV irradiation followed by dissolution-growth for the controlled synthesis of Mn-Co composite nanorings at room temperature was proposed. The nanorings structures and the process were systematically studied via TEM, HRTEM, EDX and XRD. Bir-MnO_2 nanosheets first formed through the direct photolysis of KMnO_4 under UV light irradiation. This was followed by a dissolution-growth process via the dissolution of Bir-MnO_2 nanosheets by the generated H~+ from the redox reaction between the added Co(NO_3)_2 and residual KMnO_4, as well as the accompanied formation of CoOOH, and Mn-Co composite nanorings. It was found that a balance between the dissolution and growth rate was needed. Suitable pH, KMnO_4 presence and the starting nanosheets like Bir-MnO_2 were the key factors for the formation of nanorings. The obtained Mn-Co nanorings/TiO_2 showed enhanced efficiency for the catalytic oxidation of HCHO. Based on the above understandings, it is believed that the developed dissolution-growth method can be adopted for the designing and preparation of other Mn-Co composite nanostructures which can be further applied for environmental pollution remediation.     

CaSnO_3/膨润土复合光催化剂的制备及对亚甲基蓝的光催化降解性能

采用水热合成法制备出CaSnO3/膨润土复合光催化剂,采用XRD、SEM和IR等分析手段对该样品的形貌和结构进行表征,并研究了其对亚甲基蓝水溶液的光催化降解性能.结果表明:负载比例为3%的CaSnO3/膨润土复合光催化剂对亚甲基蓝水溶液的降解效果最好,当催化剂用量为60 mg,反应时间为14 min时,降解率可达98%.     

一种2,5–取代的吡啶类药物中间体的合成

吡啶衍生物因其独特的化学结构,已被作为一类合成子广泛地应用于药物中间体的构建。以2,5–吡啶二甲酸二甲酯为原料,通过水解、酰化和还原等反应合成了一种新的2,5–取代的吡啶类药物中间体。     

氧化硅基底负载TiO2薄膜的制备及其光催化应用研究

以钛酸丁酯为钛源，乙酰丙酮和冰醋酸为水解抑制剂，聚乙二醇为致孔剂，制备了一种稳定的TiO₂水溶胶。采用浸渍提拉法将TiO₂溶胶负载到活化的载玻片上，再经180℃水热或500℃煅烧得到TiO₂薄膜催化剂。采用扫描电子显微镜（SEM）、原子力显微镜（AFM）、透射电子显微镜（TEM）、X射线晶体衍射（XRD）和Raman光谱等分析手段对样品进行了表征，结果表明：TiO₂薄膜是由粒径为8~12 nm的球形颗粒组成的多孔结构，其晶型为结晶度良好的锐钛矿。以甲基橙为光降解物，在紫外灯下测试薄膜的光催化性能，结果显示煅烧处理的TiO₂薄膜催化剂的光催化活性优于水热处理，对低浓度甲基橙的降解效率达90%以上，并且多次重复使用后光催化活性基本保持不变。     

无溶剂条件下嘧啶-6-酮衍生物的简便合成

以芳醛、氰乙酸乙酯和氰基胍为原料,氢氧化钠为催化剂,在无溶剂条件下加热,方便、高效地合成嘧啶-6-酮衍生物.这种新的合成方法具有反应时间短、条件温和、成本低和环境友好等优点.     

含均三嗪结构苯并噻唑类化合物的合成和晶体结构

以三聚氯氰等为原料合成了一种含均三嗪结构苯并噻唑类化合物（HY），并通过X射线单晶衍射对其结构进行了表征。结果表明：HY属于单斜晶体，空间群为P2（1）／”。晶胞参数为：Z=4，a=1．4278（17）nm，b=1．6690（2）nm，c=1．44842（17）nm，α=90°，β=102．707（2）°，），γ=90°，V=3．3655（7）nm^3；R1=0．0755；wR2=0．2161。